Copper-catalyzed aerobic aliphatic C–H oxygenation with hydroperoxides
نویسندگان
چکیده
We report herein Cu-catalyzed aerobic oxygenation of aliphatic C-H bonds with hydroperoxides, which proceeds by 1,5-H radical shift of putative oxygen-centered radicals (O-radicals) derived from hydroperoxides followed by trapping of the resulting carbon-centered radicals with molecular oxygen.
منابع مشابه
Copper-catalyzed oxidative oxyalkylation of enol ethers with α-amino carbonyl compounds and hydroperoxides.
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